Nmr of paramagnetic substances in solution pdf

Nmr of paramagnetic substances in solution pdf
Solution structure · NMR · Dipolar interactions · Magnetic properties Introduction One of the main bottlenecks in the area of structural biol-ogy is the development of techniques for obtaining high resolution structures in solution, so that structural modifi-cations can be followed as physical and chemical condi-tions are changed (e.g. temperature, redox potential, and added substrates or
The potential use of paramagnetic compounds as nuclear magnetic resonance (NMR) contrast agents was examined in vitro. The T1 relaxation times for serial dilutions of Cu2+, Cr3+, Fe3+, and Mn2+ ions in saline, gadolinium oxalate (a potential oral contrast agent) in suspension, and chromium EDTA (a
is paramagnetic or diamagnetic, and if it is paramagnetic, some indication of the number of unpaired electrons. The 1 H-NMR spectrum of acetylacetone is also measured as both tautomers exist in solution on the NMR
The paramagnetic ions are likely to be more mobile in these mixtures (as compared to glycerine – water mixtures) and this should reveal some interesting information on the nature of molecular
is possible to detect NMR connectivities in the vicinity of a paramagnetic center and therefore to collect a suf- ficient number of NOE constraints to solve solution
2/01/1990 · An image of the distribution of the molecules of a paramagnetic substance in solution obtained by exciting EPR resonance in the solute and obtaining an NMR image of selected nuclei (e.g. protons) in the solvent.
NMR signals from paramagnetic substances are generally more difficult to detect than those from diamagnetic compounds. This is because the hyperfine interactions between magnetic dipoles of unpaired electrons and atomic nuclei are substantially stronger than the typical nuclear spin interactions such as magnetic shielding, nuclear quadrupolar
NMR spectra of paramagnetic Co(II) and Cu(II) derivatives of Pseudomonas aeruginosa His46Asp azurin have been investigated. In each derivative, assignment of hyperfine-shifted resonances outside the diamagnetic envelope of spectra recorded at 200 and 500 MHz confirms that the Asp carboxylate is coordinated to the paramagnetic metal center.
ChemInform Abstract: NMR of Paramagnetic Substances ChemInform Abstract: NMR of Paramagnetic Substances SEVERAL AUTHORS, SEVERAL AUTHORS 1997-01-21 00:00:00 ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals.
His research interests include development of NMR-based structural methodologies in solution and in the solid state, theory of electron and nuclear relaxation, NMR of paramagnetic species, relaxometry, contrast agents, bioinorganic chemistry, metabolomics and NMR-based analytical methods. He is the author of more than 500 publications and of four books. His h-index is above 70 and his papers
PARAMAGNETIC RELAXATION REAGENTS Nuclear Magnetic Resonance Studies of Preferential Solvation Hans Grahn, NMR Research Group, Department of Organic Chemistry,
Substances in Solution by Nuclear Magnetic Resonance. By D. F. EVANS. The shifts of the proton resonance lines of inept reference molecules in solution caused by paramagnetic substances are accurately given by the theoretical espression AH/H = where AK is the change in volume susceptibility. For aqueous solutions of paramagnetic substances, about 2% of t-butyl alcohol is incorporated, and …
The EMBO Practical Course will provide theoretical and practical insights for optimal use of the protocols in order to study molecular structure and dynamics through solution and solid state NMR, using the information related to the presence of paramagnetic metal ions.
Lanthanide paramagnetic probes for NMR spectroscopic
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The solution structure of paramagnetic metalloproteins
[PDF] Solution Nmr Of Paramagnetic Molecules Applications
The shifts of the proton resonance lines of inert reference molecules in solution caused by paramagnetic substances are accurately given by the theoretical espression ΔH/H = …
nmr of biomolecules Download nmr of biomolecules or read online here in PDF or EPUB. Please click button to get nmr of biomolecules book now. All books are in clear copy here, and all files are secure so don’t worry about it.
magnetic resonance in chemistry. vol. 24, 1034-1038 (1986)
The nickel centre coordinates two bromine and two nitrogen atoms in a tetrahedral environment, and the metallacycle Ni(NN)2C adopts a boat conformation with the benzyl group in an axial position. 1H NMR studies have been carried out to characterize these paramagnetic nickel compounds in solution. Valuable information about the disposition of the ligands and dendritic wedges in solution has
the NMR spectra of paramagnetic x-complexes. This has allowed the resolution of the signal splitting of Cp This has allowed the resolution of the signal splitting of Cp deuterons of 1 and 5 which could not be observed earlier in the ‘H NMR spectra.
A study was conducted to demonstrate the application of lanthanide paramagnetic probes for nuclear magnetic resonance spectroscopic studies of molecular conformational dynamics in solution to macrocyclic molecules.
Abstract. Paramagnetic effects on nuclear relaxation processes are described in the framework of the Solomon-Bloembergen concepts. The factors contributing to nuclear relaxation, including the instantaneous electron-nuclear dipolar and contact couplings and the Curie spin effect, are described using simplified cases.
The use of pseudocontact shifts to refine solution
2.2. Humic Substances Isolation. Soil carbon content was not less than 1% in all the samples investigated. The HAs and FAs were extracted according to the procedure recommended by the IHSS . Briefly, HAs were extracted with 0.1 M NaOH (soil/solution ratio 1 : 10) under nitrogen gas.
Paramagnetic substances, for example Gd-DTPA solutions, are used as MRI oral contrast agents in gastrointestinal imaging to depict the lumen of the digestive organs. Different Gd-DTPA solutions or zeolites containing gadolinium can be used e.g., for diagnosis of delayed gastric emptying, diagnosis of Crohn’s disease etc.
Analysis of the solution conformations of T4 lysozyme by paramagnetic NMR spectroscopy† Jia-Liang Chen, a Yin Yang, a Lin-Lin Zhang, Haobo Liang, b Thomas Huber,*
NMR T 1-Relaxation Measurements on Paramagnetic Organolanthanides: an Alternative Tool for Structure Determination in Solution. Laurent BRACHAIS, [a]and Marc VISSEAUX, * [a], [b]
1209 Paramagnetic Agents for Contrast-Enhanced NMR Imaging: AReview L ValM.Runge1 Jeffrey A.Clanton1 Charles M.Lukehart2 C.Leon Partain1 A.Everette James, Jr.1
240 Bulletin of Magnetic Resonance Effect of Paramagnetic Ions in Aqueous Solution for Precision Measurement of Proton Gyromagnetic Ratio
The application of paramagnetic lanthanoid ions in NMR spectroscopy on proteins The symbol Ln is used to refer to any lanthanoid. All but one of the lanthanoids are f-block elements, so-called due to the filling of the 4f electron shell.
Paramagnetic Susceptibility by NMR sites.chem.colostate.edu
Spin transitions in spin-crossover compounds are now routinely studied in the solid state by magnetometry; however, only a few methods exist for studies in solution. The currently used Evans method, which relies on NMR spectroscopy to measure the magnetic susceptibility, requires the availability of a very pure sample of the paramagnetic
Download solution nmr of paramagnetic molecules or read online here in PDF or EPUB. Please click button to get solution nmr of paramagnetic molecules book now. All books are in clear copy here, and all files are secure so don’t worry about it.
The bulk magnetic susceptibility (BMS) shifts of 1 H NMR resonance signals for inert reference compounds caused by the addition of paramagnetic lanthanide(III) compounds were exploited in order to determine lanthanide(III) concentrations in solution. The BMS shifts of an inert reference compound in the samples were measured by comparing the chemical shifts with those of an external reference
ChemInform Abstract: 1H NMR Resonance Assignment of the Active Site Residues of Paramagnetic Proteins by 2D Bond Correlation Spectroscopy: Metcyanomyoglobin.
Solution structure of paramagnetic metalloproteins 1723 due to the ring current of the heme, and to the C(O)NH moieties, whose anisotropies in helices sum up. Indeed, cytb5 has four almost parallel helices, whose axis is nearly parallel to the heme plane. The anisotropy values and principal directions of xmol, xmetal and xdia are reported in Fig. 5 [58]. Fig. 5 Molecular and metal magnetic
To obtain solution state 13C NMR spectra that are quantitative, that is, in which peak areas or intensities are in direct proportion to the number of 13C nuclei resonating, two phenomena must be taken into consideration.
The presence of paramagnetic ions in most organometallic complexes increases the proton spectra’s chemical shift range to hundreds of ppm. However, achieving such large bandwidths at high field is a challenging task. The Magritek Spinsolve benchtop NMR spectrometer is equipped with a special
Paramagnetic substances that shorten proton T1 relaxation time have promise as nuclear magnetic resonance (NMR) contrast agents. The cardiovascular toxicity and tissue T1 response to 0.01-0.1 mM
NMR of Paramagnetic Molecules Kara L. Bren University of Rochester “NMR of Paramagnetic Substances,” Coord. Chem. Rev. 1996, 150, 1-296. • Banci, “Nuclear and Electron Relaxation. The Magnetic Nucleus-unpaired Electron Coupling in Solution,” 1991, VCH: Weinheim. ISBN: 3-5272-8306-4 • Bren, “NMR Analysis of Spin States and Spin Densities,” in Spin States in Biochemistry and
The NMR (nuclear magnetic resonance) paramagnetic relaxation enhancement (NMR- PRE) that is produced by paramagnetic solutes in solution has been investigated theoretically with respect to the influence of zero field splitting (zfs) interactions in the electron spin

Nuclear spin relaxation due to paramagnetic species in
Bertini and C. Luchinat, NMR of Paramagnetic Substances in Biological Systems (Elsevier, Amsterdam, 1996). the use of paramagnetic spin labels in protein structure determination, 3,5 3. I. Bertini, C. Luchinat, and G. Parigi, Solution NMR of Paramagnetic Molecules
with the local magnetic field calculations in paramagnetic substances were studied in papers [1 – 6]. In this paper we analyse the dependences of the NMR second moment M 2 on temperature. Beside the second mo- ment M 20 which corresponds to the nuclear dipole-dipole interactions, the Curie-Weiss constant θ and the magnetic moment µ i of paramagnetic ions may be determined from the
Paramagnetic NMR spectroscopy refers to NMR spectroscopy of paramagnetic compounds. [1] [2] Although most NMR measurements are conducted on diamagnetic compounds, paramagnetic samples are also amenable to analysis and give rise to special effects indicated by a wide chemical shift range and broadened signals.
The sums point at the types of contrast agent of the solution. For example, T1 contrast agents, such as Gd complexes, image is bright and also is known as positive contrast agent; T2 contrast agents, such as based on ion of Fe 3 O 4 super-paramagnetic magnetic contrast agents, image is dark and is known as negative contrast agent.
For paramagnetic substances, chemists sometimes compute a related number, the effective magnetic moment or μ eff, which is defined by the equation: T eff M P 8F’ where χ’ M is expressed in units of cubic centimeters per mole (cm3 mol-1) and μ eff has units of Bohr magnetons (μ B). For compounds that obey the Curie law, μ eff is a constant that is independent of temperature. There are a
NMR determination of chemically related metals in solution as a new method of inorganic analysis L. A. Fedorov V. I. Vernadsky Institute of Geochemistry and Analytical Chemistry Academy of Sciences of the USSR, SU-117975 Moscow, USSR
paramagnetic substances have been used in biomolecular NMR as intermolecular relaxation agents 4 and magnetic alignment agents facilitating the measurements of residual dipolar coup-
This experiment is designed to demonstrate the use of NMR for a purpose other than organic structure determination, to determine the magnetic susceptibilities of certain paramagnetic species in solution, to estimate the number of unpaired electrons from the molar susceptibilities, and to verifyphysical and chemical properties of water pdfNMR of Paramagnetic Molecules: Principles and Applications is a compendium of papers that discusses the physical principles behind the technique of nuclear magnetic resonance, as well as, evaluates the scope and limitation of the applications of NMR in chemistry and biology.
The NMR tube contains a solution of the paramagnetic substance with 2% reference substance (t-butanol) and the coaxial insert contains only the solvent and reference substance. d0 is the density of the solvent and ds is the density of the solution. Evans correlated and observed the difference in chemical shift of an inert reference compound (t-butanol) in the presence and absence of
Applications of Paramagnetic NMR Spectroscopy for Monitoring Transition Metal Complex Stoichiometry and Speciation Debbie C. Crans1, and supernatant solutions were used to acquire the *H NMR spectra. NMR Spectroscopy. lH NMR spectra were recorded on Varian INOVA-300 and 400 spectrometers operating at 300.118 and 400.107 MHz, respectively, and temperatures of 300 ± IK. The!H NMR …
solution NMR.’*2 In contrast, solid state NMR of paramagnetic compounds is still largely unexplored and predictions about the detection of signals are not very clear.
CHARACTERIZATION OF THE INTERNATIONAL HUMIC SUBSTANCES
Keywords: NMR; paramagnetic ions; molecular association and viscosity INTRODUCTION zyxwv The presence of paramagnetic substances in a liquid reduces the relaxation times (TI) and (T,) of nuclei of the solvent. This effect was first demonstrated by Bloch, Hansen and Packard [l] for protons in aqueous solutions of Fe3+ ions. This effect was further studied by Bloembergen, Purcell and Pound [2
Recent advances in solution NMR spectroscopy have opened the door to directly studying sparsely populated states of proteins and their complexes. There are three NMR techniques that can be used to investigate sparsely populated states with occupancies ranging from 0.5 to 5 % and lifetimes spanning nanoseconds to milliseconds.
Title: NMR Manual for Paramagnetic Susceptibility Measurement (Evans Method ) Purpose . This Evans Method manual will help NMR users understand paramagnetic susceptibility measurement by using NMR. Users can simply follow the procedures to conduct their experiments with little or even no NMR staff assistance . Introduction . Evans Method was established in 1959 for magnetic …
13/04/2015 · NMR signals from paramagnetic substances are generally more difficult to detect than those from diamagnetic compounds. This is because the hyperfine interactions between magnetic dipoles of unpaired electrons and atomic nuclei are substantially stronger than the typical nuclear spin interactions such as magnetic shielding, nuclear
Analysis of NMR and UV-visible spectra suggests a highly symmetrical structure for [LnPc 2] − in solution. Contact shifts and pseudo-contact shifts were separated from the observed paramagnetic shifts by a statistical analysis and the results compared with data from other LSR complexes.
These substances are referred to as superparamagnetic and have a magnetic susceptibility which is from 100 to 1000 times that of paramagnetic substances. They have a significantly greater effect on the image contrast (shortening of T 2 ) than do paramagnetic substances.
Download NMR of Paramagnetic Molecules: Applications to Metallobiomolecules and Models, Second Edition is a self-contained, comprehensive reference for chemists, physicists, and life scientists whose research involves analyzing paramagnetic compounds.
Solution NMR spectroscopy using paramagnetic probes offers a particularly convenient technique to investigate the topology of membrane associated proteins and peptides. It does
ChemInform Abstract NMR of Paramagnetic Substances
MRI Paramagnetic Substance p2 - MR-TIP Database
Determination of paramagnetic lanthanide(III

applicable include NMR, NQR, and ICR. A frequent problem in electron paramagnetic resonance (EPR) spectroscopy is the partial or complete overlap of signals from
A magnetic birefringence effect has been observed in solutions of paramagnetic substances, this effect being determined by the anisotropy of the magnetic moment; for compounds with a pure-spin moment, no paramagnetic effect is manifested.
and d, are the densities of pure solvent and solution; and %is the mass susceptibility of the solvent, or -0.72 x lo4 cm3 g-‘ for the dilute aqueous t-butanol.
However, NMR spectroscopy can be considered as a quantitative primary ratio method of measurement, 1,2 since the ratio of substances in a mixture can be determined directly from the NMR spectral measurement without referencing to another substance. The absolute amount of substances can be determined by using simple reference substances.
The paramagnetic metal can for example be bound to the macromolecular product by reacting the intermediate macromolecular substance containing chelate-forming groups with an excess of a water- soluble salt of the paramagnetic metal in aqueous solution at an appropriate pH-value, usually 2-7, e.g. 5-6. Purification and isolation of the product may then be performed e.g. by dialysis
Solution NMR of Paramagnetic Molecules is unique in dealing with these matters. The scope is that of presenting a complete description, which is both rigorous and pictorial, of theory and experiments of NMR of paramagnetic molecules in solution. Pertinent examples are described. From the time dependent behaviour of electrons in the various metal ions including polimetallic systems to the
Paramagnetic Effects in NMR – Outline and Useful References • Relaxation by electron spins – distance mapping • Field induced orientation – RDC measurements
Paramagnetic agents for contrast-enhanced NMR imaging a
H NMR Relaxation Studies on Glycerine-Water and Dioxan- 1
Analysis of the solution conformations of T4 lysozyme by

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NMR of paramagnetic substances (Book 1996) [WorldCat.org]

Probing Spin Crossover in a Solution by Paramagnetic NMR

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The application of paramagnetic lanthanoid ions in NMR

Paramagnetic nuclear magnetic resonance spectroscopy
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Solution NMR of Paramagnetic Molecules Volume 2 Elsevier
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Applications of Paramagnetic NMR Spectroscopy for

Lab 9 The Paramagnetic Complex Mn(acac)3
Paramagnetic nuclear magnetic resonance spectroscopy

with the local magnetic field calculations in paramagnetic substances were studied in papers [1 – 6]. In this paper we analyse the dependences of the NMR second moment M 2 on temperature. Beside the second mo- ment M 20 which corresponds to the nuclear dipole-dipole interactions, the Curie-Weiss constant θ and the magnetic moment µ i of paramagnetic ions may be determined from the
His research interests include development of NMR-based structural methodologies in solution and in the solid state, theory of electron and nuclear relaxation, NMR of paramagnetic species, relaxometry, contrast agents, bioinorganic chemistry, metabolomics and NMR-based analytical methods. He is the author of more than 500 publications and of four books. His h-index is above 70 and his papers
NMR of Paramagnetic Molecules: Principles and Applications is a compendium of papers that discusses the physical principles behind the technique of nuclear magnetic resonance, as well as, evaluates the scope and limitation of the applications of NMR in chemistry and biology.
These substances are referred to as superparamagnetic and have a magnetic susceptibility which is from 100 to 1000 times that of paramagnetic substances. They have a significantly greater effect on the image contrast (shortening of T 2 ) than do paramagnetic substances.
paramagnetic substances have been used in biomolecular NMR as intermolecular relaxation agents 4 and magnetic alignment agents facilitating the measurements of residual dipolar coup-
The application of paramagnetic lanthanoid ions in NMR spectroscopy on proteins The symbol Ln is used to refer to any lanthanoid. All but one of the lanthanoids are f-block elements, so-called due to the filling of the 4f electron shell.
magnetic resonance in chemistry. vol. 24, 1034-1038 (1986)
Solution NMR of Paramagnetic Molecules is unique in dealing with these matters. The scope is that of presenting a complete description, which is both rigorous and pictorial, of theory and experiments of NMR of paramagnetic molecules in solution. Pertinent examples are described. From the time dependent behaviour of electrons in the various metal ions including polimetallic systems to the
13/04/2015 · NMR signals from paramagnetic substances are generally more difficult to detect than those from diamagnetic compounds. This is because the hyperfine interactions between magnetic dipoles of unpaired electrons and atomic nuclei are substantially stronger than the typical nuclear spin interactions such as magnetic shielding, nuclear

Paramagnetic NMR Spectroscopy of Cobalt(II) and Copper(II
H NMR Relaxation Studies on Glycerine-Water and Dioxan- 1

Download solution nmr of paramagnetic molecules or read online here in PDF or EPUB. Please click button to get solution nmr of paramagnetic molecules book now. All books are in clear copy here, and all files are secure so don’t worry about it.
The shifts of the proton resonance lines of inert reference molecules in solution caused by paramagnetic substances are accurately given by the theoretical espression ΔH/H = …
The NMR (nuclear magnetic resonance) paramagnetic relaxation enhancement (NMR- PRE) that is produced by paramagnetic solutes in solution has been investigated theoretically with respect to the influence of zero field splitting (zfs) interactions in the electron spin
240 Bulletin of Magnetic Resonance Effect of Paramagnetic Ions in Aqueous Solution for Precision Measurement of Proton Gyromagnetic Ratio
For paramagnetic substances, chemists sometimes compute a related number, the effective magnetic moment or μ eff, which is defined by the equation: T eff M P 8F’ where χ’ M is expressed in units of cubic centimeters per mole (cm3 mol-1) and μ eff has units of Bohr magnetons (μ B). For compounds that obey the Curie law, μ eff is a constant that is independent of temperature. There are a
Title: NMR Manual for Paramagnetic Susceptibility Measurement (Evans Method ) Purpose . This Evans Method manual will help NMR users understand paramagnetic susceptibility measurement by using NMR. Users can simply follow the procedures to conduct their experiments with little or even no NMR staff assistance . Introduction . Evans Method was established in 1959 for magnetic …
1209 Paramagnetic Agents for Contrast-Enhanced NMR Imaging: AReview L ValM.Runge1 Jeffrey A.Clanton1 Charles M.Lukehart2 C.Leon Partain1 A.Everette James, Jr.1
The potential use of paramagnetic compounds as nuclear magnetic resonance (NMR) contrast agents was examined in vitro. The T1 relaxation times for serial dilutions of Cu2 , Cr3 , Fe3 , and Mn2 ions in saline, gadolinium oxalate (a potential oral contrast agent) in suspension, and chromium EDTA (a
Abstract. Paramagnetic effects on nuclear relaxation processes are described in the framework of the Solomon-Bloembergen concepts. The factors contributing to nuclear relaxation, including the instantaneous electron-nuclear dipolar and contact couplings and the Curie spin effect, are described using simplified cases.
These substances are referred to as superparamagnetic and have a magnetic susceptibility which is from 100 to 1000 times that of paramagnetic substances. They have a significantly greater effect on the image contrast (shortening of T 2 ) than do paramagnetic substances.
13/04/2015 · NMR signals from paramagnetic substances are generally more difficult to detect than those from diamagnetic compounds. This is because the hyperfine interactions between magnetic dipoles of unpaired electrons and atomic nuclei are substantially stronger than the typical nuclear spin interactions such as magnetic shielding, nuclear
The presence of paramagnetic ions in most organometallic complexes increases the proton spectra’s chemical shift range to hundreds of ppm. However, achieving such large bandwidths at high field is a challenging task. The Magritek Spinsolve benchtop NMR spectrometer is equipped with a special

NMR T1-Relaxation Measurements on Paramagnetic
NMR and Electronic Relaxation in Paramagnetic Dicopper(II

Title: NMR Manual for Paramagnetic Susceptibility Measurement (Evans Method ) Purpose . This Evans Method manual will help NMR users understand paramagnetic susceptibility measurement by using NMR. Users can simply follow the procedures to conduct their experiments with little or even no NMR staff assistance . Introduction . Evans Method was established in 1959 for magnetic …
Applications of Paramagnetic NMR Spectroscopy for Monitoring Transition Metal Complex Stoichiometry and Speciation Debbie C. Crans1, and supernatant solutions were used to acquire the *H NMR spectra. NMR Spectroscopy. lH NMR spectra were recorded on Varian INOVA-300 and 400 spectrometers operating at 300.118 and 400.107 MHz, respectively, and temperatures of 300 ± IK. The!H NMR …
His research interests include development of NMR-based structural methodologies in solution and in the solid state, theory of electron and nuclear relaxation, NMR of paramagnetic species, relaxometry, contrast agents, bioinorganic chemistry, metabolomics and NMR-based analytical methods. He is the author of more than 500 publications and of four books. His h-index is above 70 and his papers
2.2. Humic Substances Isolation. Soil carbon content was not less than 1% in all the samples investigated. The HAs and FAs were extracted according to the procedure recommended by the IHSS . Briefly, HAs were extracted with 0.1 M NaOH (soil/solution ratio 1 : 10) under nitrogen gas.
The application of paramagnetic lanthanoid ions in NMR spectroscopy on proteins The symbol Ln is used to refer to any lanthanoid. All but one of the lanthanoids are f-block elements, so-called due to the filling of the 4f electron shell.
The nickel centre coordinates two bromine and two nitrogen atoms in a tetrahedral environment, and the metallacycle Ni(NN)2C adopts a boat conformation with the benzyl group in an axial position. 1H NMR studies have been carried out to characterize these paramagnetic nickel compounds in solution. Valuable information about the disposition of the ligands and dendritic wedges in solution has
magnetic resonance in chemistry. vol. 24, 1034-1038 (1986)
Abstract. Paramagnetic effects on nuclear relaxation processes are described in the framework of the Solomon-Bloembergen concepts. The factors contributing to nuclear relaxation, including the instantaneous electron-nuclear dipolar and contact couplings and the Curie spin effect, are described using simplified cases.
ChemInform Abstract: 1H NMR Resonance Assignment of the Active Site Residues of Paramagnetic Proteins by 2D Bond Correlation Spectroscopy: Metcyanomyoglobin.
A study was conducted to demonstrate the application of lanthanide paramagnetic probes for nuclear magnetic resonance spectroscopic studies of molecular conformational dynamics in solution to macrocyclic molecules.
solution NMR.’*2 In contrast, solid state NMR of paramagnetic compounds is still largely unexplored and predictions about the detection of signals are not very clear.
The potential use of paramagnetic compounds as nuclear magnetic resonance (NMR) contrast agents was examined in vitro. The T1 relaxation times for serial dilutions of Cu2 , Cr3 , Fe3 , and Mn2 ions in saline, gadolinium oxalate (a potential oral contrast agent) in suspension, and chromium EDTA (a